[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
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چکیده
The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.
منابع مشابه
[(Z)-O-Isopropyl N-(4-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.134 (3) Å].
متن کامل[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)° for the two mol-ecules]...
متن کامل[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-κS](triphenylphosphine-κP)gold(I) dichloromethane hemisolvate
The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H⋯N, C-H⋯S and C-H⋯π inter-action...
متن کامل[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-κS](triphenylphosphine-κP)gold(I)
The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S-Au-P angle = 174.61 (4)°], with the distortion related to a short intra-molecular Au⋯O contact [2.988 (3) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis by C-H⋯π inter-actions.
متن کامل[(Z)-Ethyl N-isopropylthiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.
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